Fibaro will do this and more either using block scenes or LUA programing
Home Automation
Home automation is the residential extension of building automation.
It is automation of the home, housework or household activity.
Home automation may include centralized control of lighting, HVAC (heating, ventilation and air conditioning), appliances, security locks of gates and doors and other systems, to provide improved convenience, comfort, energy efficiency and security.
Warning: Working with electricity can result in injury, property damage, or even death if it is not done properly. Please keep this in mind while assisting others. If you are not sure about what you are doing, hire a licensed professional.
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Any proper hub can do the awake/asleep most have some form of PC integration. Amazon/apple/google pretty much exist to push product none of them have much power behind them integrate with a real hub home assistant runs fine on a 1g pi 3.
Why a button for movie mode? You can read the status of your streaming to see if it's a movie playing even get theming information.
Using streaming status is a good idea and could further automate my system. The only problem is that I wanted one button to change both the lights and also change the active monitor from my desk to the one facing my bed. It could be distracting opening a streaming service on my desktop only for the monitor to suddenly go black and turn on the other one. I also might want to open steam and not Netflix, for example. I also want to turn my scaling up on the other monitor.
These are all things less complicated using a hotkey on the PC than getting HA back into it. You can do it either way just less of a pita.
I've had good success using Hubitat. Like you I tried the Google Home path but, we soon became convinced we were being spied on via the assistant to send us advertising emails and we found it rather creepy when it would join into conversations uninvited. Gmail was another issue in business as customers with gmail addresses had emails from us manipulated to insert ads for other Google services. I don't trust "free" big tech cloud offerings. With Hubitat I have created home & business security that was both local and without subscriptions using sensors and sirens. I set up my own sprinkler timer and controls which has been very handy when working on sprinklers in the yard as I avoid trips to the garage to turn various zones on or off to flush lines & etc. by simply using a "dashboard" on my Android phone. Slightly funky interface though it offers some very powerful capabilities which I believe could perform all of the functions you describe. It is a smaller company with frequently miserable documentation and website. The community seems a bit cliquish and someone new might find themselves scolded for posting a question in the wrong group or not having read the right documentation. It works great once you figure it all out. It has integrations which allow Google or Alexa but I've never liked talking to things that aren't real people. I have a google home hub, google speaker, and google home mini all collecting dust after multiple undisclosed privacy intrusions from Google. Those were particularly irritating when emails to customers were modified without notice by Google which resulted in complaints and confusion just because the customer had a gmail address and used a Google client. 6-bit answer I guess.