I'm mostly familiar with him from his series on why all marxist revolutions were dictatorships, where he's quite scathing towards Marxism and all of its offshoots, and instead points out how Anarchist thinkers predicted all those poor outcomes, and how superior their solutions and methods were.
Overall from what I've seen of him, his opinions remind me of Bookchin's more than anything (though I'm basing that on old interviews and the few things I've read of Bookchin's).
All I remember of that show was catching it on a VHS after I left it recording to grab squidbillies one night, and there was a scene of a shark trying to start a car for a really, really long time, which was pretty damn funny.