LSF is not a distro. It is a instruction manual and teaching aid. Don't use it as a base for you main OS. And IMO Gentoo does not really teach you more then Arch does. It gives a bit of flexibility that not many care about (how things are compiled) at a very big cost (of having to compile everything yourself). I would not use either unless compiling things is your hobby.
Sure, try them in a VM if you really want to. But I would not really consider that moving on from your current distro nor do you really need to do that.