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There's hand-loading, and I strongly suspect that gunpowder is not the hardest component to manufacture.
Potassium nitrate and sulfur.
Gunpowder is the easiest part. The casing will be the hardest as you need pretty tight tolerances, but anyone who cares could have 50 trash cans full of cases in a week for a lifetime of reloading.
And if you don't have cases for reloading, you can always use a case less design, then it's just a matter of sourcing the projectile.
Of course there is always black powder, ball and cap, etc.
I have heard it before that the hardest part is getting access to reliable chemical primers. But I think if you were looking at all available options on an equal footing, you'd probably be more likely to go with some sort of electronic ignition system, or something of that nature.
Guns are ~~harder~~ easier to manufacture than cartridges. Honestly, when civil war finally does break out it will be ammunition, not guns, that the government restricts access to because that's way easier to control and way harder to manufacture. Reloading still needs brass and primers, and those are hard to make for anything outside of a shotgun.
Edit: said exactly the opposite of what I intended to say.