Proxmox doesn't come with Linux packages needed for a NAS, like Samba and NFS servers, installed out of the box. There's also no web user interface for managing NAS functionality. Since Proxmox is based on Debian, the components needed for a NAS can be installed from Debian repositories, but their configuration and management would be through the command line. If you're considering a virtualized NAS for Proxmox, I suggest looking into Starwind CVM or TrueNAS as a VM option. Both support ZFS.
Unraid, on the other hand, comes prepackaged as a NAS, complete with a web user interface for management. As Unraid is also Linux-based, it offers virtualization capabilities similar to Proxmox, including KVM and VirtIO. A notable difference is in their containerization approach: Proxmox uses Linux Containers (LXC), while Unraid opts for Docker Containers.
I suppose you could deploy an HA cluster using either Ceph or StarWind VSAN HA storage technology. These solutions replicate data across cluster nodes, ensuring your VMs are highly available. They both fit Proxmox.